The Conformations of Some gem-Dimethyl Substituted Cyclic Anhydrides.
نویسندگان
چکیده
منابع مشابه
The Cope rearrangement of gem-dimethyl substituted divinylcyclopropanes.
The reactivity of a range of substituted divinylcyclopropanes towards the thermal Cope rearrangement has been examined. The effects of gem-dimethyl substitution on the cyclopropane, the alkene geometry, the relative stereochemistry of the cyclopropane and the steric and electronic effects of a range of functional groups were all examined, and the methods developed were used to synthesise a rang...
متن کاملCyclic Oligophosphonic Anhydrides Stable in Aqueous Media
Depending on reaction conditions, the phosphonylation of N-alkylacetamides with H3PO3-P C I3 in B-HC1 media (B = Py, Bu3N) gives either l-alkylaminoethylidene-l,l-bisphosphonic acids (la—e) or previously unknown l-alkylaminobutane-l,l,3,3-tetrayl-tetrakisphosphonic dianhydrides (2a-e). The latter convert into monocyclic forms (3a-e) under mild acidic hydrolysis. Acyclic forms (4a-e) cannot be i...
متن کاملAsymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines.
Asymmetric addition of arylboronates to aryl-substituted cyclic ketimines proceeded in the presence of a rhodium catalyst coordinated with a chiral diene ligand to give high yields of sulfamidates and sulfamides with high enantioselectivity (up to 99% ee).
متن کاملAcetylation of Some Cyclic Enamines With Substituted Acetyl Chlorides
Acylation reaction of a variety of cyclic ketones via acylation of the corresponding enamines is welldefined in the literature. Enamine acylation of carbonyl compounds is a significant synthetic method because of its mildness and the ease of preparing various β-diketones [1-4]. Acylation reactions are performed by means of converting enamines to the enaminoketones and subsequent hydrolysis of t...
متن کاملextensions of some polynomial inequalities to the polar derivative
توسیع تعدادی از نامساوی های چند جمله ای در مشتق قطبی
15 صفحه اولذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1974
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.28b-0013